Radiation Induced Functional Modifications of Engineering Polymers/ SSNTDs and Their Potential Applications
In this talk we are briefly described the basic methods of radiation/ion beam-induced modification of engineering polymers and their applications. Swift Heavy Ion and Gamma irradiation techniques are playing a crucial role for modifications in structural, chemical, optical and surface morphological properties of materials [1-4]. The energy loss of the incident ions described by the mean depth at which particle is embedded. Trajectory of incident ion described by the elastic and inelastic collision, high energetic ions (>2MeV) interact in elastically with the target and electronic energy stopping (Se) occur similarly low energetic ions (It has been well established that when polymers are subjected to radiations (ions or gamma radiations), the processes like radical formation, chain scission, cross-linking, formation of double or triple bonds, etc. take place with the emission of light gaseous products. The efficiency of these modifications depends on the structure of materials/polymers and the ion beam parameter (energy, fluence, mass, charge etc.) and nature of the target. Positron Annihilation Lifetime Spectroscopy (PALS) is a unique, non- destructive technique and capable of determining size distribution, fraction and density of free volume holes in polymers. Ortho-positronium (o-Ps) pick off annihilation lifetime, the long-lived component in the lifetime spectra, is very sensitive to structural changes in the polymers and is correlated directly to the free volume hole size. The industrial and biomedical high grade quality polymers were purchased from Good fellow, U.K. and Bayer A.G., Germany and some polymers were synthesized by chemical method. Solid State Nuclear Track Detectors were irradiated and exposed to gamma radiation at different fluencies and different doses at Variable Energy Cyclotron Centre (VECC), Kolkata, India and Inter University Accelerator Centre, New Delhi, India. After modified engineering polymers/materials by SHI and Gamma radiation were characterized by different techniques such as: Positron Annihilation Lifetime Spectroscopy (PALS), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and UV-visible Spectroscopy [5-11]. The aim is to investigate the behaviour of the effects of the irradiation as well as gamma radiation as the size of the nano scale free volume in SSNTD’s material is varied. The results will be discussed during the presentation.
References:
- Rajesh Kumar, P. Singh: Applied Surface Science: 337 (2015)19-26 (Elsevier).
- P. Singh, Rajesh Kumar, R.Singh, A. Roychowdhury, D. Das: Applied Surface Science 328 (2015) 482-490 (Elsevier).
- S. K.Gupta, P.Singh, R.Singh, Rajesh Kumar: Advances in Polymer Technology: DOI 10.1002/adv.21518(1-7) (Wiley)
- S. K. Gupta, P. Singh, Rajesh Kumar: Vacuum 121(2015)177-186 (Elsevier).
- Vishnu Chauhan and Rajesh Kumar, Materials Chemistry and Physics, 240 (2020) 122127, (Elsevier).
- Vishnu Chauhan, Deepika Gupta, N. Koratkar, and Rajesh Kumar, Scientific Reports, 11 (2021)1-16 (Springer).
- Rajesh Kumar, Vishnu Chauhan et al. Journal of Alloys and Compounds, 831 (2020) 154698, (Elsevier).
- Vishnu Chauhan, Rajesh Kumar, et al., Ceramics International, 45 (2019) 18887-18898 (Elsevier).
- Rajesh Kumar, Vishnu Chauhan et al., Physics Letters A 383 (2019) 9601 (Elsevier).
- P. Singh, Rajesh Kumar, P.M.G.Nambissan: Vacuum 115(2015)31-38 (Elsevier).
- P. Singh, Rajesh Kumar, Jincemon Cyriac, M.T. Rahul, P.M.G. Nambissan, R. Prasad: Nucl. Instr. Meth. B 320, (2014)64-69(Elsevier)